FISHER SCIENTIFIC -- INDIGO CARMINE, S71306, I166 25, I166-25, I16625 -- -
===================== Product Identification ===================== Product ID:INDIGO CARMINE, S71306, I166 25, I166-25, I16625 MSDS Date:12/02/1998 FSC:NIIN:Submitter:N EN Status Code:A MSDS Number: CLDPJ === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIRLAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100/703-527-3887 Resp. Party Other MSDS Num.:60300 Chemtrec Ind/Phone:(800)424-9300 CAGE:18464 === Contractor Identification === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410 Country:US Phone:201-796-7100 CAGE:18464 ============= Composition/Information on Ingredients ============= Ingred Name:C.I. ACID BLUE 74. (EINECS# 212-728-8) (HAZARD SYMBOLS: XN. RISK PHRASES: 22) CAS:860-22-0 RTECS #:DU3000000 = Wt:100. Other REC Limits:NIOSH: NONE LISTED OSHA PEL:NONE LISTED ACGIH TLV:NONE LISTED ===================== Hazards Identification ===================== LD50 LC50 Mixture:CAS# 860-22-0 ORAL, RAT: LD50=2 GM/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: CAUTION! MAY BE HARMFUL IF SWALLOWED. MAY CAUSE EYE AND SKIN IRRITATION, RESPIRATORY AND DIGESTIVE TRACT IRRITATION. TARGET ORGANS: NONE. POTENTIAL HEALTH EFFECTS: EYE: THIS PRODUC T CONTAINS A CATIONIC DYE. SIMILAR DYES HAVE CAUSED PERMANENT INJURY TO CORNEA AND CONJUNCTIVA IN DOCUMENTED EXPOSURE CASES WITH HUMAN OR RABBIT EYES. SKIN: MAY CAUSE SKIN IRRITATION. INGESTION: MAY C AUSE GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING AND DIARRHEA. MAY BE HARMFUL IF SWALLOWED. INHALATION: MAY CAUSE RESPIRATORY TRACT IRRITATION. CHRONIC: NO INFORMATION FOUND. Explanation of Carcinogenicity:NOT LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA. Effects of Overexposure:SEE HEALTH HAZARDS ACUTE AND CHRONIC. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING UPPER/LOWER EYELIDS. GET MEDICAL AID. SPEEDY ACTION IS CRITICAL! SKIN: GET MEDICAL AID IF IRRITATION DEVELOPS OR PERSISTS . FLUSH SKIN WITH PLENTY OF SOAP AND WATER. INGESTION: IF VICTIM IS CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. GET MEDICAL AID. INHALAT ION: REMOVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING DIFFICULT, GIVE OXYGEN. GET MEDICAL AID. NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY. ANTI DOTE: NONE REPORTED. ===================== Fire Fighting Measures ===================== Flash Point:NOT AVAILABLE Lower Limits:NOT AVAILABL Upper Limits:NOT AVAILABL Extinguishing Media:INCASE OF FIRE, USE WATER, DRY CHEMICAL, CHEMICAL FOAM OR ALCOHOL-RESISTANT FOAM. Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH APPROVED, AND FULL PROTECTIVE GEAR. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN CONTROL MEASURES SECTION. CLEAN UP SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS IN PROTECTIVE EQUIPMENT SECTION. SWEEP UP OR ABSORB MATERIAL, THEN PLACE IN SUITABLE CLEAN, DRY, CLOSED CONTAINER FOR DISPOSAL. AVOID GENERATING DUSTY CONDITIONS. PROVIDE VENTILATION. ====================== Handling and Storage ====================== Handling and Storage Precautions:HANDLING: WASH THOROUGHLY AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. USE WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. KEEP CONTAINER TIGHTLY CLOSED. AVOID INGESTION AND INHALATION. STORAGE: STORE IN COOL, DRY, WELL-VENTILATED (OTHER PRECAUTIONS) Other Precautions:HANDLING/STORAGE (CONT'D): AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP CONTAINERS TIGHTLY CLOSED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS OR EUROPEAN STANDARD EN 149 MU ST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS LOW. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKER GOGGLES . WEAR APPROPRIATE (SUPPL SAFETY) Other Protective Equipment:APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Supplemental Safety and Health EYE PROTECTION (CONT'D): PROTECTIVE EYEGLASSES OR CHEMICAL SAFETY GOGGLES AS DESCRIBED BY OSHA'S EYE AND FACE PROTECTION REGULATIONS IN 29 CFR 1910.133 OR EUROPEAN STANDARD EN166 (MFR). ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NOT AVAILABLE Melt/Freeze Pt:>350.C, 662.F Decomp Temp:Decomp Text:NOT AVAILABLE Vapor Pres:NEGLIGIBLE Vapor Density:NOT AVAIL Spec Gravity:NOT AVAILABLE pH:NOT AVAILABLE Viscosity:NOT AVAILABLE Evaporation Rate & Reference:NEGLIGIBLE Solubility in Water:SLIGHTLY SOLUBLE IN WATER Appearance and Odor:DARK BLUE SOLID; NO REPORTED ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS, DUST GENERATION. Hazardous Decomposition Products:NITROGEN OXIDES, CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:LD50/LC50: ORAL, MOUSE: LD50=2500 MG/KG; ORAL, RAT: LD50=2 GM/KG. EPIDMIOLOGY: TUMORIGENIC DATA EXISTS FOR INDIGO CARMINE. TERATOGENICITY, REPRODUCTIVE EFFECTS, NEUROTOXICITY: NO INFORMATION FOUND. MU TAGENICITY: STUDIES HAVE BEEN PERFORMED WITH LABORATORY ANIMALS. OTHER STUDIES: NO DATA AVAILABLE. C.I. ACID BLUE 74: NOT LISTED BY ACGIH, IARC, NIOSH, NTP OR OSHA. ===================== Ecological Information ===================== Ecological:ECOTOXICITY: NOT AVAILABLE. ENVIRONMENTAL FATE: NO INFORMATION FOUND. PHYSICAL/CHEMICAL: NO INFORMATION FOUND. OTHER: NOT AVAILABLE. RCRA U-SERIES: NONE LISTED. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE AND LOCAL REGULATIONS. RCRA P-SERIES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:U.S. D.O.T. - NO INFORMATION AVAILABLE. IMO: NOT REGULATED AS A HAZARDOUS MATERIAL. IATA: NOT REGULATED AS A HAZARDOUS MATERIAL. RID/ADR: NOT REGULATED AS A HAZARDOUS MATERIAL. CANADIAN TDG: NO INFOR MATION AVAILABLE. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ), 302 (TPQ): NONE OF CHEMICALS IN MATERIAL HAVE RQ OR TPQ. SECTION 313: NO CHEMICALS REPORTABLE UNDER SECTION 313. FEDERAL REGULATORY (CONT'D): POLLUTANTS UNDER CWA: NONE OF CHEMICALS IN PRODUCT ARE LISTED AS TOXIC POLLUTANTS UNDER CWA. OSHA: NONE OF CHEMICALS IN PRODUCT CONSIDERED HIGHLY HAZARDOUS BY OSHA. EUROPEAN/INTERNATIONAL REGULATIONS: EUROPEAN LABELING IN ACCORDANCE WITH E C DIRECTIVES: HAZARD SYMBOLS: XN. RISK PHRASES: R 22: HARMFUL IF SWALLOWED. WGK (WATER DANGER/PROTECTION): CAS# 860-22-0: 1. CANADA: CAS# 860-22-0 LISTED ON CANADA'S (OTHER INFO) Federal Regulatory Information:TSCA: CAS# 860-22-0 LISTED ON TSCA INVENTORY. HEALTH & SAFETY REPORTING LIST: NONE OF CHEMICALS ARE ON HEALTH & SAFETY REPORTING LIST. CHEMICAL TEST RULES: NO CHEMICALS IN PRODUCT ARE UNDER A CHEMICAL TEST RULE. SECTION 12B: NONE OF CHEMICALS LISTED UNDER TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF CHEMICALS IN MATERIAL HAVE A SNUR UNDER TSCA. CLEAN AIR ACT: MATERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS, CLASS 1 OR CLASS 2 OZONE DEPLETORS. CLEAN WATER ACT: NONE OF CHEMICALS IN PRODUCT LISTED AS HAZARDOUS SUBSTANCES UNDER CWA NOR LISTED AS PRIORITY. (SARA) State Regulatory Information:C.I. ACID BLUE 74 NOT PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL OR NJ. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF CHEMICALS IN PRODUCT ARE LISTED. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.